Iranian Journal of Chemistry

Iranian Journal of Chemistry

Synthesis, structure, and catalytic activity of new polyoxomolybdate C22H47Mo4N12O15 in azide-alkyne cycloaddition reaction.

Document Type : Original Article

Authors
Asmaa Yousofvanda 1
Mojtaba Amini 2
Mojtaba Hosseinifard 3
Jan Janczak 4
1 Department of Physical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran
2 University of Tabriz
3 بلوار 29 بهمن- دانشگاه تبریز- دانشکده شیمی- گروه شیمی معدنی- دکتر مجتبی امینی
4 Polish Academy of Sciences
10.22036/cr.2023.408553.1220
Abstract
New polyoxomolybdate with formula (C7H15N4)3[CH2Mo4O15] (1) was synthesized by a simple method in one step. The structure of the synthesized polyoxo molybdate was investigated by single crystal X-ray crystallographic analysis, which indicates the presence of three cations of N-methyl erroptropin (C7H15N4)+ and polyanion [CH2Mo4O15]3- in the structure 1. In the polyanion [CH2Mo4O15]3-, molybdenum metals are surrounded by two terminal and two bridging μ2-oxygen atoms, one μ4- bridging hydroxyl ligand and also one oxygen of the methanediol ligand is coordinated to each molybdenum metal. After optimizing the reaction conditions for a model reaction, polyoxomolybdate 1 was used as a homogeneous and efficient catalyst for the azide- alkyne ring addition reaction to produce various 1,2,3- triazoles without adding another substance as a reducing agent with medium to high efficiency. In order to check the homogeneity or heterogeneity of the catalyst in the reaction solution, the reaction was stopped after one hour and the catalyst was completely centrifuged and separated from the solution and the reaction was then continued for another 1 h and the results showed that the catalyst was dissolved in the reaction solvent, thus confirming the homogeneity of the catalyst.

Graphical Abstract

Synthesis, structure, and catalytic activity of new polyoxomolybdate C22H47Mo4N12O15 in azide-alkyne cycloaddition reaction.
Keywords
Polyoxomolybdate' Catalytic activity'Azide-alkyne cycloaddition'1
2
3-Triazole

Subjects

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Iranian Journal of Chemistry
Volume 6, Issue 2 - Serial Number 11
December 2023
Pages 217-222

  • Receive Date 30 July 2023
  • Revise Date 05 September 2023
  • Accept Date 11 September 2023