Synthesis and Charactrization of Palladium Nanocatalyst Stabilized on Graphitic Carbon Nitride Support: an Efficient Heterogeneous Catalyst in Suzuki Coupling Reaction in Water

Bazyar, Zahra

doi:10.22036/cr.2024.449422.1242

Synthesis and Charactrization of Palladium Nanocatalyst Stabilized on Graphitic Carbon Nitride Support: an Efficient Heterogeneous Catalyst in Suzuki Coupling Reaction in Water

Document Type : Original Article

Author

Zahra Bazyar

Behbahan Khatam Alanbia University of Technology

10.22036/cr.2024.449422.1242

Abstract

The Suzuki coupling reaction as an effective method, has found numerous applications in the development of the pharmaceutical industry. In this study a simple and efficient method for carbon-carbon bond formation reaction using a heterogeneous palladium nano catalyst supported on graphitic carbon nitride (Pd/g-C3N4) without the use of ligands was employed with phenylboronic acid and various aryl haledes in an aqueous environment. All reaction was carried out under optimal conditions in a water/ethanol solvent at 80 C, and in the presence of 0.02 g of catalyst with good to excellent yields. This method can effectively be used for a range of active and inactive aryl haledes. Pd/g-C3N4 not only exhibited high catalytic performance but can also be recovered four times. The Pd/g-C3N4 was characterized using some different techniques, including scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), inductively coupled plasma (ICP) and Brunauer-Emmett-Teller (BET).
Keywords: Suzuki coupling reaction, Palladium, Heterogeneous catalyst, catalyst

Graphical Abstract

Synthesis and Charactrization of Palladium Nanocatalyst Stabilized on Graphitic Carbon Nitride Support: an Efficient Heterogeneous Catalyst in Suzuki Coupling Reaction in Water

Keywords

Suzuki coupling reaction

Palladium

Heterogeneous catalyst

catalyst

Subjects

Organic Chemistry

[1] Y. Zang, S. Gao, B. Jing, H. Sun, J. Wang, J. Liu, F. Miao, L. Xu, J. Mater. Sci. 58, 170 (2023).

[2] K. R. Chaudhari, A. P. Wadawale, A. K. Pathak, S. Dey, Inorg. Chem. 63, 1427 (2024).

[3] Y. Zhou, L. Qiu, J. Li, W. Xie, J. Am. Chem. Soc. 145, 28146 (2023).

[4] K. Islam, V. Arora, B. Vikas; Nag, A. Kumar, ChemCatChem. 14, 202200440 (2022).

[5] M. Neysi, D. Elhamifar, Front. Chem. 11, 1112911 (2023).

[6] S. Kargar, D. Elhamifar, Materials Today Chemistry. 17, 100318 (2020).

[7] A. K. King, A. Brar, G. Li, M. Findlater, Organometallics. 42, 2353 (2023).

[8] Y. Watanabe, H. Morozumi, H. Mutoh, K. Hagiwara, M. Inoue, Angew. Chem. 135, 202309688 (2023).

[9] A. Ahmed, I. Mushtaq, S. Chinnam, future j. pharm. sci. 9, 67 (2023).

[10] C. Palladino, T. Fantoni, L.Ferrazzano, A. Tolomelli, W. Cabri, ACS Sustain. Chem. Eng. 11, 15994 (2023).

[11] L. Riva,G. Nicastro, M. Liu, C. Battocchio, C. Punta, A. Sacchetti, Gels 8, 789 (2022).

[12] J. Lakshmidevi, B. R. Naidu, K. Venkateswarlu, Mol. Catal. 522, 112237 (2022).

[13] S. Nasr, Journal of Electronic Materials 52, 5362 (2023).

[14] K. Matsubara, K. Tomomatsu, A. Tajiri, A. Watanabe, Y. Koga, R. Ishikawa, Y. Yamada, Eur. J. Inorg. Chem. 2022, 202100870 (2022).

[15] K. Goswami, D. Das, P. Bera, S. Roy, M. M. Seikh, P. K. Sinha, A. Gayen, J. Mol. Struct. 1299, 137136 (2024).

[16] T. Suzuki, K. Tanaka, C. Wakabayashi, E. Saita, M. Yoshida, Nat. Chem. Biol. 10, 930 (2014).

[17] F. Dehghani Firuzabadi, Z. Asadi, Inorg. Nano. Met. 1 (2023).

[18] H. Maati, O. Amadine, Y. Essamlali, I. Ayouch, H. Mahi, K. Abdelouahdi, M. Zahouily, J. Mol. Struct. 1294, 136347 (2023).

[19] A. Mastalir, A. Molnár, ChemCatChem. 15, 202300643 (2023).

[20] M. Ashraf, M. S. Ahmad, Y. Inomata, N. Ullah, M. N. Tahir, T. Kida, Coord. Chem. Rev. 476, 214928 (2023).

[21] M.Shaker, D. Elhamifar, New J. Chem. 44, 3445 (2020),

[22] M. Neysi, D. Elhamifar, Sci. Rep. 12, 7970 (2022).

[23] M.Shaker, D. Elhamifar, Mater. Today Chem. 18, 100377 (2020).

[24] M. Hosseini‐Sarvari, Z. Bazyar, Chem. Select 3, 1898 (2018).

[25] J. Wen, J. Xie, X. Chen, X. Li, Appl. Surf. Sci. 391, 72 (2017).

[26] T. P. Vijayakumar, M. D. Benoy, J. Duraimurugan, G. S. Kumar, M. Shkir, P. Maadeswaran, A. S. Kumar, K. A. R. Kumar, Diamond Related Mater. 121, 108735 (2022).

[27] X. Zhao, J. Xie, X. Liu, X. Liu, Appl Organometal Chem. 33, e4623 (2019).